近两百年长江中下游典型城郊湖泊沉积物重金属污染历史和来源研究——以安庆石塘湖为例
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中国科学院南京地理与湖泊研究所

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国家自然科学基金项目(面上项目,重点项目,重大项目)


Study on the history and sources of heavy metal pollution in sediments of a typical suburban lake in the middle and lower Yangtze River over the past two centuries: A case study of Shitang Lake
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Nanjing Institute of Geography and Limnology, Chinese Academy of Sciences

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The National Natural Science Foundation of China (General Program, Key Program, Major Research Plan)

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    摘要:

    城郊型湖泊受农业扩展和城市化加速的双重影响,面临日益加剧的重金属污染问题,威胁水生态系统及周边人类健康。本研究以长江中下游典型城郊湖泊石塘湖为研究对象,通过沉积岩芯采集和年代序列建立,结合粒度组分和元素浓度分析,采用富集系数法和潜在生态风险指数法,评估并重建了近两百年来Cd、As、Pb、Co、Cu、Ni、Cr和Zn的污染历史。此外,利用相关性分析、聚类分析和正定矩阵因子分析法解析了重金属的来源及其相对贡献率。研究表明,大部分重金属(如As、Pb、Co、Cu、Ni、Cr和Zn)的污染等级较低,潜在生态风险轻微;然而,Cd的污染等级和潜在生态风险较高,自1981年起由无污染至较轻污染上升至中等污染,2004年达到强生态风险等级。此外,自20世纪70年代中期以来,沉积物综合潜在生态风险指数显著上升,但总体风险仍处于轻微水平。污染来源分析显示,1930年之前,石塘湖沉积物中的重金属主要来源于自然风化(平均贡献率为63.63%),工业源和农业源的贡献率分别为25.22%和11.15%;1930年至1974年,农业源上升至23.44%,而自然源和工业源的平均贡献率分别为51.72%和24.84%;1975年以后,农业源和工业源贡献率分别上升至46.74%和41.19%,成为主要污染来源。本研究为石塘湖流域的重金属污染防治提供了科学依据,为长江中下游湖泊生态环境保护提供了长期变化视角,同时也为其他发展中国家和地区在快速城镇化背景下的城郊型湖泊污染防治提供了理论参考和技术支持。

    Abstract:

    Suburban lakes, under the dual influence of agricultural expansion and accelerated urbanization, are facing increasingly severe heavy metal pollution, posing threats to aquatic ecosystems and surrounding human health. This study focuses on Shitang Lake, a typical suburban lake in the middle and lower reaches of the Yangtze River. Through sediment core sampling and chronological reconstruction, combined with grain size and elemental concentration analysis, the enrichment factor method and potential ecological risk index were employed to assess and reconstruct the pollution history of Cd, As, Pb, Co, Cu, Ni, Cr, and Zn over the past two centuries. Additionally, correlation analysis, cluster analysis, and positive matrix factorization were used to determine the sources of heavy metals and their relative contributions. The results show that most heavy metals (e.g., As, Pb, Co, Cu, Ni, Cr, and Zn) exhibited low pollution levels and slight ecological risks. However, Cd had significantly higher pollution levels and potential ecological risks, increasing from no pollution to moderate pollution starting in 1981, with strong ecological risk levels reached in 2004. Furthermore, since the mid-1970s, the comprehensive potential ecological risk index of the sed-iment has risen significantly, although the overall risk remains at a slight level. Source analysis revealed that before 1930, heavy metals in Shitang Lake sediments primarily originated from natural weathering (average contribution rate of 63.63%), while industrial and agricultural sources contributed 25.22% and 11.15%, respectively. From 1930 to 1974, the contribution of agricultural sources increased to 23.44%, while natural and industrial sources accounted for 51.72% and 24.84%, respectively. After 1975, the contributions of agricultural and industrial sources rose to 46.74% and 41.19%, becoming the main sources of pollution. This study provides a scientific basis for the prevention and control of heavy metal pollution in the Shitang Lake basin, offers a long-term perspective for the ecological protection of lakes in the middle and lower reaches of the Yangtze River, and serves as a theoretical reference and technical support for managing suburban lake pollution in other developing countries and regions under rapid urbanization.

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  • 收稿日期:2024-11-12
  • 最后修改日期:2025-07-20
  • 录用日期:2025-01-24
  • 在线发布日期: 2025-04-17
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